Current knowledge about the reaction mechanisms of various metalloenzymes and catalysts demonstrates that substrate conversions occurring at the metal center are controlled by secondary interactions. Such secondary interactions comprise all properties within the ligands of a coordination compound --[...]
Organosulfur compounds play a major role in asymmetric synthesis and their applications and scope are manifold: Chiral sulfoxides, ylids, sulfonamides and many more reagents are used for elegant, effective synthesis and catalytic reactions. Thus, organosulfur compounds enormously widen the possibili[...]